My use case was as follows:
Start Active@ File Recovery
Press the "Search" button in the menu bar's middle.
Enter the file format (*.pst), press "Find" and then navigate to the file using the explorer like view. From here, one can either inspect the MFT record or the raw data of the file.
When inspecting the file's data one should refer to Microsoft's documentation about PST files (Outlook Personal Folders (.pst) File Format). The formentioned document about file recovery contains some very helpful information about MFT records.
Below, is the beginning of the raw data. Notice the marker "!BDN" at the beginning of the PST's header.
One thing, before starting your attemp to recover your lost file, I would read the "How to recover NTFS (Freeware Guide)" first. There are some "Don'ts", like don't install any new software onto the same drive, you should read before starting.